Scientists discover new class of semiconducting entropy-stabilized materials
Crystal construction of GeSnPbSSeTe, a semiconducting entropy-stabilized chalcogenide alloy. The yellow atoms are cations (Ge, Sn, Pb) and the blue atoms are anions (S, Se, Te). The distinction in lightness corresponds to totally different species of the anions and cations. The configurational entropy from the dysfunction of each the anion and the cation sublattices stabilizes the single-phase rocksalt strong answer, as demonstrated from first-principles calculations in addition to experimental synthesis and characterization. Credit score: Logan Williams, Emmanouil Kioupakis, and Zihao Deng, Dept. of Supplies Science & Engineering, College of Michigan

Semiconductors are essential supplies in quite a few purposeful functions akin to digital and analog electronics, photo voltaic cells, LEDs, and lasers. Semiconducting alloys are notably helpful for these functions since their properties could be engineered by tuning the blending ratio or the alloy components. Nonetheless, the synthesis of multicomponent semiconductor alloys has been an enormous problem attributable to thermodynamic section segregation of the alloy into separate phases. Just lately, College of Michigan researchers Emmanouil (Manos) Kioupakis and Pierre F. P. Poudeu, each within the Supplies Science and Engineering Division, utilized entropy to stabilize a brand new class of semiconducting supplies, based mostly on GeSnPbSSeTe high-entropy chalcogenide alloys, a discovery that paves the best way for wider adoption of entropy-stabilized semiconductors in purposeful functions. Their article, “Semiconducting high-entropy chalcogenide alloys with ambi-ionic entropy stabilization and ambipolar doping” was just lately revealed within the journal Chemistry of Supplies.

Entropy, a thermodynamic amount that quantifies the diploma of dysfunction in a fabric, has been exploited to synthesize an enormous array of novel supplies by mixing eachcomponent in an equimolar trend, from high-entropy metallic alloys to entropy-stabilized ceramics. Regardless of having a big enthalpy of blending, these supplies can surprisingly crystalize in a single crystal construction, enabled by the massive configurational entropy within the lattice. Kioupakis and Poudeu hypothesized that this precept of entropy stabilization could be utilized to beat the synthesis challenges of semiconducting alloys that favor to segregation into thermodynamically extra secure compounds. They examined their speculation on a 6-component II-VI chalcogenide alloy derived from the PbTe construction by mixing Ge, Sn, and Pb on the cation web site, and S, Se, and Te on the anion web site.

Utilizing excessive throughput first-principles calculations, Kioupakis uncovered the advanced interaction between the enthalpy and entropy in GeSnPbSSeTe high-entropy chalcogenide alloys. He discovered that the massive configurational entropy from each anion and cation sublattices stabilizes the alloys into single-phase rocksalt strong options on the progress temperature. Regardless of being metastable at room temperature, these strong options could be preserved by quick cooling beneath ambient circumstances. Poudeu later verified the idea predictions by synthesizing the equimolar composition (Ge1/3Sn1/3Pb1/3S1/3Se1/3Te1/3) by a two-step solid-state response adopted by quick quenching in liquid nitrogen. The synthesized energy confirmed well-defined XRD patterns akin to a pure rocksalt construction. Moreover, they noticed reversible section transition between single-phase strong answer and multiple-phase segregation from DSC evaluation and temperature dependent XRD, which is a key characteristic of entropy stabilization.

What makes high-entropy chalcogenide intriguing is their purposeful properties. Beforehand found high-entropy supplies are both conducting metals or insulating ceramics, with a transparent dearth within the semiconducting regime. Kioupakis and Poudeu discovered that. the equimolar GeSnPbSSeTe is an ambipolarly dopable semiconductor, with proof from a calculated band hole of 0.86 eV and signal reversal of the measured Seebeck coefficient upon p-type doping with Na acceptors and n-type doping with Bi donors. The alloy additionally displays an ultralow thermal conductivity that’s almost unbiased of temperature. These fascinating purposeful properties make GeSnPbSSeTe a promising new materials to be deployed in digital, optoelectronic, photovoltaic, and thermoelectric gadgets.

Entropy stabilization is a basic and highly effective technique to understand an enormous array of supplies compositions. The invention of entropy stabilization in semiconducting chalcogenide alloys by the group at UM is barely the tip of the iceberg that may pave the best way for novel purposeful functions of entropy-stabilized supplies.

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Extra info:
Zihao Deng et al, Semiconducting Excessive-Entropy Chalcogenide Alloys with Ambi-ionic Entropy Stabilization and Ambipolar Doping, Chemistry of Supplies (2020). DOI: 10.1021/acs.chemmater.0c01555

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Scientists uncover new class of semiconducting entropy-stabilized supplies (2020, August 1)
retrieved 1 August 2020

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